Aromatic Azo- and Benzidine-Based Substances

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Azo Direct Dyes

Monoazo Direct Dyes
Substances Colour Index (C.I.) Information [1] Empirical Data Availability [***] Section 71
Chemical Abstracts Service Registry Number (CAS RN) Domestic Substances List (DSL) Name C.I. Generic Name(s) C.I. Consti-
tution Number(s)
Other CASNo. Asso-
ciated with C.I. name / number
Physical-Chemical Properties Ecolo-
gical End-
points
Health End-
points
Water Solu-
bility
Log Kow Mel-
ting / Decom-
posi-
tion point
1325-37-7 C.I.Direct Yellow 11 C.I.Direct Yellow 11 C.I.40000  98171621, 65150803 -- -- -- X X Y
6471-09-6 Benzoic acid, 5-[[4-[[4-[[4-[(4-amino-9,10-dihydro-9,10-dioxo-3-sulfo-1-anthracenyl)amino]-2-sulfophenyl]amino]-6-(phenylamino)-1,3,5-triazin-2-yl]amino]phenyl]azo]-2-hydroxy-, trisodium salt C.I.Direct Green 28 C.I.14155  -- -- -- X X -- Y
10114-47-3 7-Benzothiazolesulfonic acid, 2,2’-(azodi-4,1-phenylene)bis[6-methyl-, disodium salt -- -- -- -- -- -- -- -- Y
65150-80-3 C.I.Direct Yellow 11, lithium salt   C.I.Direct Yellow 11, lithium salt   -- -- X -- -- -- -- Y
71033-21-1 Benzothiazolesulfonic acid, 2,2’-(azodi-4,1-phenylene)bis[6-methyl-, disodium salt -- -- -- -- -- -- -- -- Y
Disazo Direct Dyes
Substances Colour Index (C.I.) Information [1] Empirical Data Availability [***] Section 71
Chemical Abstracts Service Registry Number (CAS RN) Domestic Substances List (DSL) Name C.I. Generic Name(s) C.I. Consti-
tution Number(s)
Other CASNo. Asso-
ciated with C.I. name / number
Physical-Chemical Properties Ecolo-
gical End-
points
Health End-
points
Water Solu-
bility
Log Kow Mel-
ting / Decom-
posi-
tion point
2829-42-7 Benzoic acid, 3,3’-[carbonylbis(imino-4,1-phenyleneazo)]bis[6-hydroxy-, disodium salt C.I.Direct Yellow 26 C.I.25300  25849267 -- -- -- X -- Y
2870-32-8 Benzenesulfonic acid, 2,2’-(1,2-ethenediyl)bis[5-[(4-ethoxyphenyl)azo]-, disodium salt C.I.Direct Yellow 12 C.I.24895  -- X -- -- X -- Y
3214-47-9 1,5-Naphthalenedisulfonic acid, 3,3’-[carbonylbis[imino(2-methyl-4,1-phenylene)azo]]bis-, tetrasodium salt C.I.Direct Yellow 50 C.I.29025  25738243 -- -- -- X -- Y
3626-36-6 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[4-hydroxy-3-(phenylazo)-, disodium salt C.I.Direct Orange 26 C.I.29150  25188232 X -- -- X X Y
3687-80-7 1-Naphthalenesulfonic acid, 4-[[1-hydroxy-6-[[[[5-hydroxy-6-[(2-methoxyphenyl)azo]-7-sulfo-2-naphthalenyl]amino]
carbonyl]amino]-3-sulfo-2-naphthalenyl]azo]-, trisodium salt
C.I.Direct Red 26 C.I.29190  25188356 -- -- -- -- -- Y
5001-72-9 2-Naphthalenesulfonic acid, 7,7’-iminobis[4-hydroxy-3-(phenylazo)-, disodium salt C.I.Direct Red 31 C.I.29100  25188378 -- -- -- X -- Y
5489-77-0 2-Naphthalenesulfonic acid, 3-[[4-[(2,4-dimethyl-6-sulfophenyl)azo]-2-methoxy-5-methylphenyl]azo]-4-hydroxy-7-(phenylamino)-, disodium salt C.I.Direct Violet 51 C.I.27905  25188538 X -- -- -- -- Y
6420-33-3 1,5-Naphthalenedisulfonic acid, 3,3’-[carbonylbis[imino(5-methoxy-2-methyl-4,1-phenylene)azo]]bis-, tetrasodium salt C.I.Direct Yellow 34 C.I.29060  -- -- -- -- -- X Y
6420-41-3 2-Naphthalenesulfonic acid, 4-hydroxy-7-[[[[5-hydroxy-6-(phenylazo)-7-sulfo-2-naphthalenyl]amino]
carbonyl]amino]-3-[(6-sulfo-2-naphthalenyl)azo]-, trisodium salt
C.I.Direct Red 4 C.I.29165  25188276 -- -- -- -- -- Y
6420-43-5 2-Naphthalenesulfonic acid, 4-hydroxy-7-[[[[5-hydroxy-6-[(2-methylphenyl)azo]-7-sulfo-2-naphthalenyl]amino]
carbonyl]amino]-3-[(2-methyl-4-sulfophenyl)azo]-, trisodium salt
C.I.Direct Red 62 C.I.29175  -- -- -- -- -- -- Y
12217-64-0 1,3-Naphthalenedisulfonic acid, 7,7’-[carbonylbis[imino(5-methoxy-2-methyl-4,1-phenylene)azo]]bis-, tetrasodium salt C.I.Direct Orange 72 C.I.29058  -- -- -- -- -- -- Y
28706-21-0 1,3-Naphthalenedisulfonic acid, 7,7’-[iminobis[carbonyl(2-methyl-4,1-phenylene)azo]]bis-, tetrasodium salt -- -- -- -- -- -- -- -- Y
38801-08-0 Benzoic acid, 4,4’-[carbonylbis[imino(1-hydroxy-3-sulfo-6,2-naphthalenediyl)azo]]bis-, compd. with 2,2’,2’’-nitrilotris[ethanol] (1:4) -- -- -- -- -- -- -- -- Y
53523-90-3 Benzoic acid, 3,3’-[1,2-ethenediylbis[(3-sulfo-4,1-phenylene)azo]]bis[6-hydroxy-5-methyl-, tetralithium salt -- -- -- -- -- -- -- -- Y
72139-21-0 Benzoic acid, 3,3’-[(1,4-dioxo-2-butene-1,4-diyl)bis(imino-4,1-phenyleneazo)]bis[6-hydroxy-, disodium salt -- -- -- -- -- -- -- -- Y
72152-50-2 Benzoic acid, 2-[[6-[[4-
[[6-(benzoylamino)-1-hydroxy-3-sulfo-2-naphthalenyl]azo]-3-methylbenzoyl]amino]-1-hydroxy-3-sulfo-2-naphthalenyl]azo]-, trisodium salt
-- -- -- -- -- -- -- -- Y
72245-49-9 Benzoic acid, 4-[[1-hydroxy-6-[[[[5-hydroxy-6-[(2-methyl-4-sulfophenyl)azo]-7-sulfo-2-naphthalenyl]amino]
carbonyl]amino]-3-sulfo-2-naphthalenyl]azo]-, sodium salt
-- -- -- -- -- -- -- -- Y
72749-87-2 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[4-hydroxy-3-[(2-methylphenyl)azo]-, disodium salt -- -- -- -- -- -- -- -- Y
72749-88-3 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[4-hydroxy-3-[(2-methoxyphenyl)azo]-, disodium salt -- -- -- -- -- -- -- -- Y
72869-93-3 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[4-hydroxy-3-[(6-sulfo-2-naphthalenyl)azo]-, compd. with 2,2’-(methylimino)bis[ethanol] (1:4) -- -- -- -- -- -- -- -- Y
75768-93-3 2-Naphthalenesulfonic acid, 7-(benzoylamino)-4-hydroxy-3-[[4-[(4-sulfophenyl)azo]phenyl]azo]-, compd. with 2,2’,2’’-nitrilotris[ethanol] (1:2) C.I.Direct Red 81 triethanolamine salt[2] -- -- X -- -- -- -- Y
83221-53-8 Benzoic acid, 5-[[4-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-1-naphthalenyl]azo]-2-hydroxy-, sodium salt -- -- -- -- -- -- -- -- Y
83221-54-9 Benzoic acid, 3-[[4-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-1-naphthalenyl]azo]-2-hydroxy-, sodium salt -- -- -- -- -- -- -- -- Y
83221-56-1 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[4-hydroxy-3-(phenylazo)-, sodium salt -- -- -- -- -- -- -- -- Y
83221-73-2 Benzoic acid, 4,4’-[carbonylbis[imino(1-hydroxy-3-sulfo-6,2-naphthalenediyl)azo]]bis-, sodium salt -- -- -- -- -- -- -- -- Y
83221-74-3 Benzoic acid, 4-[[1-hydroxy-6-[[[[5-hydroxy-6-(phenylazo)-7-sulfo-2-naphthalenyl]amino]
carbonyl]amino]-3-sulfo-2-naphthalenyl]azo]-, sodium salt
-- -- -- -- -- -- -- -- Y
83232-28-4 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[3-[[4-(acetylamino)phenyl]azo]-4-hydroxy-, sodium salt -- -- -- -- -- -- -- -- Y
83232-29-5 2-Naphthalenesulfonic acid, 3-[[4-(acetylamino)phenyl]azo]-4-hydroxy-7-[[[[5-hydroxy-6-(phenylazo)-7-sulfo-2-naphthalenyl]amino]
carbonyl]amino]-, sodium salt
-- -- -- -- -- -- -- -- Y
83232-30-8 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[4-hydroxy-3-[(2-methylphenyl)azo]-, sodium salt -- -- -- -- -- -- -- -- Y
83232-31-9 2-Naphthalenesulfonic acid, 7,7’-(carbonyldiimino)bis[4-hydroxy-3-[(2-methyl-4-sulfophenyl)azo]-, sodium salt -- -- -- -- -- -- -- -- Y
83232-32-0 2-Naphthalenesulfonic acid, 4-hydroxy-7-[[[[5-hydroxy-6-[(2-methylphenyl)azo]-7-sulfo-2-naphthalenyl]amino]
carbonyl]amino]-3-[(2-methyl-4-sulfophenyl)azo]-, sodium salt
-- -- -- -- -- -- X X Y
83783-94-2 2,7-Naphthalenedisulfonic acid, 3,3’-[1,2-ethenediylbis[(3-sulfo-4,1-phenylene)azo]]bis[5-amino-4-hydroxy-, lithium sodium salt, compd. with 2,2’-(methylimino)bis[ethanol] -- -- -- -- -- -- -- -- Y
83783-95-3 2-Naphthalenesulfonic acid, 3,3’-[1,2-ethenediylbis[(3-sulfo-4,1-phenylene)azo]]bis[6-amino-4-hydroxy-, lithium sodium salt, compd. with 2,2’-(methylimino)bis[ethanol] -- -- -- -- -- -- -- -- Y
83783-96-4 2,7-Naphthalenedisulfonic acid, 5-amino-3-[[4-[2-[4-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-2-sulfophenyl]ethenyl]-3-sulfophenyl]azo]-4-hydroxy-, lithium sodium salt, compd. with 2,2’-(methylimino)bis[ethanol] -- -- -- -- -- -- -- -- Y
83783-99-7 Benzoic acid, 3,3’-[1,2-ethenediylbis[(3-sulfo-4,1-phenylene)azo]]bis[6-hydroxy-5-methyl-, lithium sodium salt, compd. with 2,2’-(methylimino)bis[ethanol] -- -- -- -- -- -- -- -- Y
85269-31-4 Benzoic acid, 3,3’-[1,2-ethenediylbis[(3-sulfo-4,1-phenylene)azo]]bis[6-hydroxy-5-methyl-, potassium salt, compd. with 2,2’,2’’-nitrilotris[ethanol] -- -- -- -- -- -- -- -- Y
110152-63-1 Benzenesulfonic acid, 2,2’-(1,2-ethenediyl)bis[5-[(4-hydroxyphenyl)azo]-, lithium sodium salt -- -- -- -- -- -- -- -- Y
Polyazo Direct Dyes
Substances Colour Index (C.I.) Information [1] Empirical Data Availability [***] Section 71
Chemical Abstracts Service Registry Number (CAS RN) Domestic Substances List (DSL) Name C.I. Generic Name(s) C.I. Consti-
tution Number(s)
Other CASNo. Asso-
ciated with C.I. name / number
Physical-Chemical Properties Ecolo-
gical End-
points
Health End-
points
Water Solu-
bility
Log Kow Mel-
ting / Decom-
posi-
tion point
1325-54-8 C.I.Direct Orange 39 C.I.Direct Orange 39 C.I.40215 -- -- -- -- -- -- Y
4399-55-7 1,5-Naphthalenedisulfonic acid, 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-6-sulfo-1-naphthalenyl]azo]-1-naphthalenyl]azo]-, tetrasodium salt C.I.Direct Blue 71 C.I.34140  87440968 X -- -- -- -- Y
6406-87-7 2-Naphthalenesulfonic acid, 5-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-8-[[4-(phenylazo)-7-sulfo-1-naphthalenyl]azo]-, trisodium salt -- -- -- -- -- -- -- -- Y
6476-10-4 2-Naphthalenesulfonic acid, 8-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-5-[[4-(phenylazo)-6-sulfo-1-naphthalenyl]azo]-, trisodium salt -- -- -- -- -- -- -- -- Y
10134-33-5 2-Naphthalenesulfonic acid, 8-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-5-[[4-(phenylazo)-7-sulfo-1-naphthalenyl]azo]-, trisodium salt -- -- -- -- -- -- -- -- Y
10482-42-5 2-Naphthalenesulfonic acid, 5-[(7-amino-1-hydroxy-3-sulfo-2-naphthalenyl)azo]-8-[[4-(phenylazo)-6-sulfo-1-naphthalenyl]azo]-, trisodium salt -- -- -- -- -- -- -- -- Y
32829-81-5 Benzenesulfonic acid, 2,2’-(1,2-ethenediyl)bis[5-[[4-[(4-sulfophenyl)azo]phenyl]azo]-, tetrasodium salt -- -- -- -- -- -- -- -- Y
71767-19-6 2-Naphthalenesulfonic acid, 5-[[6-amino-1-hydroxy-3-sulfo-5-[(3-sulfophenyl)azo]-2-naphthalenyl]azo]-6-methoxy-8-[[7-sulfo-4-[(3-sulfophenyl)azo]-1-naphthalenyl]azo]-, pentasodium salt -- -- -- -- -- -- -- -- Y
71873-49-9 Benzoic acid, 4,4’-[1,2-ethenediylbis[(3-sulfo-4,1-phenylene)-ONN-azoxy-4,1-phenyleneazo]]bis-, tetrasodium salt -- -- -- -- -- -- -- -- Y
72245-56-8 2,7-Naphthalenedisulfonic acid, 4-amino-3-[[4-[[[4-[(2,4-diaminophenyl)azo]phenyl]
amino]carbonyl]phenyl]azo]-5-hydroxy-6-(phenylazo)-, sodium salt
-- -- -- -- -- -- -- -- Y
75150-14-0 1,4-Benzenedisulfonic acid, 2-[[4-[[4-[[1-hydroxy-6-(phenylamino)-3-sulfo-2-naphthalenyl]azo]-1-naphthalenyl]azo]-6-sulfo-1-naphthalenyl]azo]-, ammonium sodium salt -- -- -- -- -- -- -- -- Y
83221-68-5 2-Naphthalenesulfonic acid, 6-[(2,4-diaminophenyl)azo]-3-[[4-[[4-[[7-[(2,4-diaminophenyl)azo]-1-hydroxy-3-sulfo-2-naphthalenyl]azo]phenyl]
amino]-3-sulfophenyl]azo]-4-hydroxy-, trilithium salt
-- -- -- -- -- -- -- -- Y
83221-69-6 2-Naphthalenesulfonic acid, 6-[(2,4-diaminophenyl)azo]-3-[[4-[[4-[[7-[(2,4-diaminophenyl)azo]-1-hydroxy-3-sulfo-2-naphthalenyl]azo]phenyl]
amino]-3-sulfophenyl]azo]-4-hydroxy-, lithium sodium salt
-- -- -- -- -- -- -- -- Y
83221-72-1 2,7-Naphthalenedisulfonic acid, 4-amino-3,6-bis[[4-[(2,4-diaminophenyl)azo]phenyl]azo]-5-hydroxy-, lithium sodium salt -- -- -- -- -- -- -- -- Y
84878-16-0 2,7-Naphthalenedisulfonic acid, 4-amino-6-[[4-[[4-[(2,4-dihydroxyphenyl)azo]
phenyl]thio]phenyl]azo]-5-hydroxy-3-[(4-nitrophenyl)azo]-, sodium salt
-- -- -- -- -- X X -- Y
84878-17-1 2,7-Naphthalenedisulfonic acid, 4-amino-6-[[4-[[[4-[(2,4-dihydroxyphenyl)azo]phenyl]
amino]sulfonyl]phenyl]azo]-5-hydroxy-3-[(4-nitrophenyl)azo]-, potassium salt
-- -- -- -- -- -- X X Y
85169-18-2 Glycine, N-[4-[[2-[4-[[1-amino-8-hydroxy-7-(phenylazo)-3,6-disulfo-2-naphthalenyl]azo]phenyl]-1H-benzimidazol-5-yl]azo]-3-hydroxyphenyl]-, compd. with 2,2’-iminobis[ethanol] (1:3) -- -- -- -- -- -- -- -- Y
93803-37-3 2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-3-[[4-[5-[(4-hydroxyphenyl)azo]-1H-benzimidazol-2-yl]phenyl]azo]-6-(phenylazo)-, disodium salt -- -- -- -- -- -- -- -- Y
102082-94-0 2,7-Naphthalenedisulfonic acid, 4-amino-6-[[4-[[[4-[(2,4-diaminophenyl)azo]phenyl]
amino]sulfonyl]phenyl]azo]-5-hydroxy-3-[(4-nitrophenyl)azo]-, lithium salt
-- -- -- -- -- -- -- -- Y

Notes and Legend

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2026-10-08