Non-confidential summary of information received from the second phase of the Domestic Substances List Inventory Update

Purpose

In an effort to increase public awareness and to facilitate access to information on manufactured and/or imported substances in Canada, this document provides a summary of information collected by the Government of Canada under the Notice with respect to certain substances on the Domestic Substances List (DSL) that was published in the Canada Gazette in December 2012. This document refers to both information provided in mandatory responses to the notice, and information provided on a voluntary basis. The information that was collected for the 2011 calendar year will be used to update the commercial status of remaining priority substances, inform priority setting, support risk assessment and risk management activities and inform the next phase of the DSL Inventory Update (DSL IU).

To complement this summary, the Non-confidential information received from the DSL IU2 is available in EXCEL format.

Please note that the information presented in this document is limited to what was requested in the notice and throughout the document confidential business information (CBI) has been protected (i.e., by providing quantity ranges, or excluding data elements that were designated by submitters as CBI). Consequently, this may have led to underestimates, so conclusions should be drawn with care.

Background

The Domestic Substances List (DSL) was first compiled in the early 1990’s to identify substances that were in commerce in Canada between 1984 and 1986. As commercial activities with some substances can vary greatly over time, the DSL information becomes dated and no longer represents current commercial activity in Canada. The work to update the DSL, undertaken under the Chemicals Management Plan (CMP) is conducted in phases.  The first phase of the DSL IU was conducted in 2009 to determine the commercial status in 2008 of approximately 500 inanimate substances. An Update of Approximately 500 inanimate substances (chemicals) on the Domestic Substances List (Information Summary) is available.

In December 2012, a notice was issued for the second phase of the DSL IU (DSL IU2) in the Canada Gazette, Part I: Vol. 146, No. 48 - December 1,2012 under section 71 of the Canadian Environmental Protection Act, 1999 (CEPA 1999). The notice applied to approximately 2,700 substances and collected information from the 2011 calendar year.

Prior to launching the notice, the Government of Canada held consultations with various stakeholders, including industry, non-governmental organizations and other interested parties to discuss the approach to gathering information on the remaining priority existing substances. The feedback provided during these consultations aided in the development of the overall approach for the DSL IU2. In order to streamline the reporting requirements to address reporting challenges, the Government of Canada tailored the DSL IU2 notice to ensure the focus was on areas of greatest interest. As such, manufactured items included in the notice were limited to categories with greatest potential for exposure. In addition, a tiered approach was used requiring only basic non-quantitative information for substances present in reportable manufactured items, low concentrations and for polymers.

Additional information on the DSL IU2 notice can be found in the Guidance Document for completing the CEPA section 71 Notice.

Summary of information collected

Overview of substances reported

It was determined that approximately half the substances included in the DSL IU2 notice were not reported. The Substances for which no information was submitted under Phase 2 of the DSL Inventory Update is available. These substances will be examined under the Rapid Screening and Polymer Approaches.

Table 1: Snapshot of data received for DSL IU2
Data Received Number of Substances
Included in the notice 2663
Reported (via mandatory &/or voluntary submission) 1338
Not reported 1325
Manufactured or Imported in a concentration greater than or equal to 0.1% by weight (w/w) 748
Solely manufactured 81
Solely imported 506
Intended for use in commercial activities 659
Intended for use in consumer activities 437
Intended for use by or for children 204
Manufactured or Imported in a reportable manufactured item 467
Manufactured or Imported in a trace concentration (less than 0.1% w/w) 404
Solely as a contaminant/by-product 196
Solely as a waste 11
Table 2: Submissions received for DSL IU2 (includes mandatory and voluntary submissions)
Type of Submission Number of Submissions Received
Section 71 Notice 531
Declaration of Stakeholder Interest 116
Table 3: Substances reported in DSL IU2 (via mandatory and/or voluntary submissions)
Type of Substance Number of Substances Included in the Notice Number of Substances Reported Number of Substances Not Reported
Polymers 559 298 261
Non-polymers 2018 1020 998
Confidential masked substances 86 20 66

Polymers

The notice requested basic, non-quantitative information on polymers that will contribute to the Polymer approach in the next phase of the CMP.

Table 4: The 10 polymer substances most frequently reported as manufactured or imported in quantities greater than 1000 kg
CAS RN Substance Name
25322-68-3 Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-
63148-62-9 Siloxanes and Silicones, di-Me
9003-11-6 Oxirane, methyl-, polymer with oxirane
9010-79-1 1-Propene, polymer with ethene
9003-07-0 1-Propene, homopolymer
9003-55-8 Benzene, ethenyl-, polymer with 1,3-butadiene
24937-78-8 Acetic acid ethenyl ester, polymer with ethene
25068-38-6 Phenol, 4,4’-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane
9038-95-3 Oxirane, methyl-, polymer with oxirane, monobutyl ether
67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica

Substances in reportable manufactured items

The notice requested non-quantitative information for substances that were manufactured or imported in a manufactured item, and focused on categories of manufactured items with a higher potential for exposure (e.g. intended to be used by children under the age of 6 years; clothing or footwear; bedding, sleeping bags or towels, specific food packaging, reusable food or beverage containers, etc.). The 10 categories of manufactured items that were reportable in DSL IU2 are listed in Schedule 1 of the Notice with respect to certain substances on the Domestic Substances List.

Table 5: The 10 substances most frequently reported as manufactured or imported in reportable manufactured items in quantities greater than 100 kg, and some of their applications. The order in the table is based on the number of times an application was reported and is not based on the quantity in commerce.
CAS RN Substance Name Most Frequently Reported Applications of the Substances Contained in Reportable Manufactured Items
67-63-0 2-Propanol
  1. Paints and Coatings
  2. Cleaning and Furnishing Care
  3. Personal Care
14807-96-6 Talc (Mg3H2(SiO3)4)
  1. Personal Care
  2. Paints and Coatings
  3. Plastic and Rubber materials
1344-28-1 Aluminum oxide (Al2O3)
  1. Paints and Coatings
  2. Adhesives and Sealants
  3. Building or Construction Materials
7664-38-2 Phosphoric acid
  1. Paints and Coatings
  2. Cleaning and Furnishing Care
  3. Food and Beverage
128-37-0 Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-
  1. Lubricants and Greases
  2. Personal Care
  3. Ink, Toner and Colourants
79-10-7 2-Propenoic acid
  1. Adhesives and Sealants
  2. Paints and Coatings
  3. Cleaning and Furnishing Care
100-51-6 Benzenemethanol
  1. Paints and Coatings
  2. Personal Care
  3. Adhesives and Sealants
7439-96-5 Manganese
  1. Metal materials
  2. Building or Construction Materials
  3. Automotive, Aircraft and Transportation
102-71-6 Ethanol, 2,2’,2’’-nitrilotris-
  1. Personal Care
  2. Cleaning and Furnishing Care
  3. Lubricants and Greases
1328-53-6 C.I. Pigment Green 7
  1. Paints and Coatings
  2. Ink, Toner and Colourants
  3. Plastic and Rubber materials
Table 6: The 10 applications most frequently reported for substances contained in reportable manufactured items in quantities greater than 100 kg and the number of substances reported for each application
Applications of the Substances Contained in Reportable Manufactured Items Number of Substances
Personal Care 158
Paints and Coatings 101
Lubricants and Greases 81
Laundry and Dishwashing 79
Cleaning and Furnishing Care 71
Air Care 56
Metal materials 56
Adhesives and Sealants 55
Plastic and Rubber materials 48
Automotive, Aircraft and Transportation 46

Substances in trace concentrations [less than 0.1% by weight (w/w)]

The notice requested basic, non-quantitative information for substances that were manufactured or imported in a mixture or product at a concentration less than 0.1% w/w.

Table 7: Number of substances reported in trace concentrations (less than 0.1% w/w) in mixtures or products, and amount manufactured or imported solely as a contaminant, by-product or waste
Substances Reported in Trace Concentrations Number of Substances
Manufactured or imported in a trace concentration  in mixtures or products 404
solely manufactured or imported in trace concentrations 22Footnote Table 7[a]
solely manufactured or imported as a contaminant / by- product 196
solely manufactured or imported as a  waste 11

Substances in concentrations greater than or equal to 0.1% w/w

The notice requested more detailed information, such as quantitative information, for substances that were manufactured or imported alone, in a mixture, or in a product in concentrations greater than or equal to 0.1% w/w.  A total of 748 substances were reported as manufactured or imported at a concentration greater than or equal to 0.1% w/w during the 2011 calendar year, and 273 of these substances were solely reported in DSL IU2 as being manufactured or imported at a concentration greater than or equal to 0.1%.

Table 8: The top 5 substances imported in concentrations greater than or equal to 0.1% (alone or in mixture/product) based on the total quantities reported, and some of their applications (Quantities reflect volume ranges in order to protect CBI)
Rank CAS RN Substance Name 2011 Imported Quantity Range (millions of kg)  Applications
1 7697-37-2 Nitric acid 1,000 - 24,999
  1. Paints and Coatings
  2. Cleaning and Furnishing Care
  3. Agricultural Products, mixtures or manufactured items (non-pesticidal)
2 1344-28-1 Aluminum oxide (Al2O3) 1,000 - 24,999
  1. Paints and Coatings
  2. Adhesives and Sealants
  3. Building or Construction Materials
3 65996-77-2 Coke (coal) 500 - 749
  1. Raw materials
  2. Fuels and Related Products, mixtures or manufactured items
  3. Metal materials
4 1317-40-4 Copper sulfide (CuS) 100 - 249
  1. Metal materials
5 12125-02-9 Ammonium chloride ((NH4)Cl) 100 - 249
  1. Oil and Natural Gas Extraction
  2. Personal Care
  3. Adhesives and Sealants
Table 9: The top 10 substances manufactured in concentrations greater than or equal to 0.1% w/w (alone or in mixture/product) based on the total quantities reported, and some of their applications (Quantities reflect volume ranges in order to protect CBI)
Rank CAS RN Substance Name 2011 Manufactured Quantity Range (millions of kg) Applications
1 129618-34-4 Electrolytes, nickel-manufg. 1,000 - 24,999 CBI
2 74-84-0 Ethane 1,000 - 24,999
  1. Fuels and Related Products, mixtures or manufactured items
  2. Oil and Natural Gas Extraction
3 128704-79-0 Leach solutions, zinc refining 1,000 - 24,999
  1. Other metal processes
4 65996-77-2 Coke (coal) 1,000 - 24,999
  1. Raw materials
  2. Fuels and Related Products, mixtures or manufactured items
  3. Metal materials
5 69012-24-4 Wastewater, zinc sulfate electrolytic, acid 1,000 - 24,999
  1. Other metal processes
6 69011-86-5 Zinc ores, concs., preleached 1,000 - 24,999
  1. Metal materials
7 65996-69-2 Slags, ferrous metal, blast furnace 1,000 - 24,999
  1. Adhesives and Sealants
  2. Building or Construction Materials
  3. Paints and Coatings
8 65996-71-6 Slags, steelmaking 1,000 - 24,999
  1. Building or Construction Materials
9 68131-30-6 Sulfite liquors and Cooking liquors, green 1,000 - 24,999
  1. Paints and Coatings
  2. Other intermediate chemical
10 69012-79-9 Calcines, zinc ore-conc.
  1. - 999
  1. Metal materials
Table 10: The 10 sectorsFootnote Table 10[a] most frequently reported for substances that were manufactured or imported in concentrations greater than or equal to 0.1% w/w (alone or in mixture/product), and the top substances reported for each sector
NAICS Codes Industry Sector CAS RN Substance Name
4184
418410
Chemical (except agricultural) and allied product merchant wholesalers 67-63-0
14807-96-6
7664-38-2
2-Propanol
Talc (Mg3H2(SiO3)4)
Phosphoric acid
32551
325510
Paint and coating manufacturing 67-63-0
14807-96-6
872-50-4
2-Propanol
Talc (Mg3H2(SiO3)4)
2-Pyrrolidinone, 1-methyl-
325999 Other chemical product manufacturing - All other miscellaneous chemical product manufacturing 67-63-0
7664-38-2
872-50-4
2-Propanol
Phosphoric acid
2-Pyrrolidinone, 1-methyl-
32561
325610
Soap and cleaning compound manufacturing 67-63-0
68603-42-9
64-02-8
2-Propanol
Amides, coco, N,N-bis(hydroxyethyl)
Glycine, N,N’-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt
32519
325190
Basic chemical manufacturing - Other basic organic chemical manufacturing 67-63-0
9016-45-9
112-34-5
2-Propanol
Poly(oxy-1,2-ethanediyl), α-(nonylphenyl)-ω-hydroxy-
Ethanol, 2-(2-butoxyethoxy)-
336110 Automobile and light-duty motor vehicle manufacturing 108-10-1
1344-28-1
98-82-8
2-Pentanone, 4-methyl-
Aluminum oxide (Al2O3)
Benzene, (1-methylethyl)-
32562
325620
Toilet preparation manufacturing 67-63-0
102-71-6
36653-82-4
2-Propanol
Ethanol, 2,2’,2’’-nitrilotris-
1-Hexadecanol
32521
325210
Resin and synthetic rubber manufacturing 14807-96-6
67-63-0
128-37-0
Talc (Mg3H2(SiO3)4)
2-Propanol
Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-
32552
325520
Adhesive manufacturing 14807-96-6
1344-28-1
27138-31-4
Talc (Mg3H2(SiO3)4)
Aluminum oxide (AI203)
Propanol, oxybis-, dibenzoate
32411
324110
Petroleum refineries 1344-28-1
67-63-0
98-82-8
Aluminum oxide (Al2O3)
2-Propanol
Benzene, (1-methylethyl)-
Table 11: The 10 functions most frequently reported for substances that were manufactured or imported in concentrations greater than or equal to 0.1% w/w (alone or in mixture/product), and the number of substances reported for each category
Substance Function Category Number of Substances Reported
Intermediates 222
Paint additives and coating additives 186
Processing aids, not otherwise covered 145
Lubricants and lubricant additives 143
Adhesives and sealant substances 133
Processing aids, specific to petroleum production 110
Surface active agents 103
Corrosion inhibitors and anti-scaling agents 91
Solvents (which become part of formulation or mixture)               90
Pigments 89
Table 12: The 10 consumer and commercial applications most frequently reported for substances that were manufactured or imported in concentrations greater than or equal to 0.1% w/w (alone or in mixture/product), and the number of substances reported for each application

Consumer & Commercial Applications
Number of Substances Reported
Paints and Coatings 258
Lubricants and Greases 156
Adhesives and Sealants 149
Plastic and Rubber materials 146
Personal Care 140
Cleaning and Furnishing Care 137
Automotive, Aircraft and Transportation 132
Building or Construction Materials 132
Ink, Toner and Colourants 118
Oil and Natural Gas Extraction 114
Table 13: Intended uses of substances that were manufactured or imported in concentrations greater than or equal to 0.1% w/w (alone or in a mixture/product)
Intended Use Number of Substances
Intended for use in commercial activities 659
Intended for use in consumer activities 437
Intended for use by or for children (up to 14 years of age) 204
Table 14: The 10 substances most frequently reported as manufactured or imported in concentrations greater than or equal to 0.1% w/w (alone or in a mixture/product) intended for use by or for children (up to 14 years of age)
CAS RN Substance Name
67-63-0 2-Propanol
14807-96-6 Talc (Mg3H2(SiO3)4)
102-71-6 Ethanol, 2,2’,2’’-nitrilotris-
128-37-0 Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-
64-02-8 Glycine, N,N’-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt
7664-38-2 Phosphoric acid
151-21-3 Sulfuric acid monododecyl ester sodium salt
111-42-2 Ethanol, 2,2’-iminobis-
7681-57-4 Disulfurous acid, disodium salt
36653-82-4 1-Hexadecanol
Table 15: The 10 substances most frequently reported as manufactured or imported in concentrations greater than or equal to 0.1% w/w (alone or in a mixture/product) intended for use in commercial activities

CAS RN
Substance Name
67-63-0 2-Propanol
14807-96-6 Talc (Mg3H2(SiO3)4)
1344-28-1 Aluminum oxide (Al2O3)
7664-38-2 Phosphoric acid
102-71-6 Ethanol, 2,2’,2’’-nitrilotris-
34590-94-8 Propanol, 1(or 2)-(2-methoxymethylethoxy)-
64-02-8 Glycine, N,N’-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt
111-42-2 Ethanol, 2,2’-iminobis-
128-37-0 Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-
872-50-4 2-Pyrrolidinone, 1-methyl-
Table 16: The 10 substances most frequently reported as manufactured or imported in concentrations greater than or equal to 0.1% w/w (alone or in a mixture/product) intended for use in consumer activities

CAS RN
Substance Name
67-63-0 2-Propanol
14807-96-6 Talc (Mg3H2(SiO3)4)
102-71-6 Ethanol, 2,2’,2’’-nitrilotris-
1344-28-1 Aluminum oxide (Al2O3)
151-21-3 Sulfuric acid monododecyl ester sodium salt
64-02-8 Glycine, N,N’-1,2-ethanediylbis[N-(carboxymethyl)-, tetrasodium salt
7664-38-2 Phosphoric acid
128-37-0 Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-
100-51-6 Benzenemethanol
2082-79-3 Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, octadecyl ester

Moving forward

The information that was collected will be used to:

Future phases of the IU will establish a mechanism to monitor the commercial status of substances in Canada. This work will inform priority setting activities, support the operational needs in risk assessment and risk management, and will consider international decisions on substances.  Furthermore, the Government of Canada is committed to continuing to communicate results of future inventory updates in order to increase transparency and public knowledge of chemicals in commerce in Canada.

Contact us

If you have questions on DSL IU2, or wish to be engaged in discussions about the third phase of the DSL IU, please Contact Us via the Substances Management Information Line.


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