Global warming potentials

All greenhouse gases (GHGs) are not equal. Each one has a unique atmospheric lifetime and heat-trapping potential.

The Global Warming Potential (GWP) metric examines each greenhouse gas’s ability to trap heat in the atmosphere compared to carbon dioxide (CO2). We measure this over a specified time horizon. Often, we calculate GHG emissions in terms of how much CO2 is essential to produce a similar warming effect over the chosen time horizon. This is the carbon dioxide equivalent (CO2 eq) value. We calculate it by multiplying the amount of gas by its accompanying global warming potential (GWP).

The Intergovernmental Panel on Climate Change (IPCC) provided 100-year GWPs in its Fourth Assessment Report (SAR). These GWPs are consistent with Decision 18/CMA.1 They are required for inventory reporting under the United Nations Framework Convention on Climate Change (UNFCCC). GWPs are also required to be used for facility GHG reporting under Section 46 (S.46) of the Canadian Environmental Protection Act.  The updated values from the IPCC’s Fifth Assessment report will apply to facility GHG reporting, starting with reporting for the calendar year 2022.

Global warming potentials for greenhouse gases

Intergovernmental Panel on Climate Change IPCC Global Warming Potentials - 100-Year Time Horizon
Greenhouse Gas Formula Fourth Assessment Reporta Fifth Assessment Reportb
Carbon dioxide CO2 1 1
Methane CH4 25 28
Nitrous oxide N2O 298 265
Sulphur hexafluoride SF6 22 800 23 500
Nitrogen trifluoride NF3 17 200 16 100

a Data source: IPCC's Fourth Assessment Report - Errata (IPCC 2012).

b Data source: IPCC, 2013: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp.  

Hydrofluorocabons (HFCs) IPCC Global Warming Potentials - 100-Year Time Horizon
Greenhouse Gas Formula Fourth Assessment Reporta Fifth Assessment Reportb
HFC-23 CHF3 14 800 12 400
HFC-32 CH2F2 675 677
HFC-41 CH3F 92 116
HFC-43-10mee CF3CHFCHFCF2CF3 1 640 1 650
HFC-125 CHF2CF3 3 500 3 170
HFC-134 CHF2CHF2 1 100 1 120
HFC-134a CH2FCF3 1 430 1 300
HFC-143 CH2FCHF2 353 328
HFC-143a CH3CF3 4 470 4 800
HFC-152 CH2FCH2F 53 16
HFC-152a CH3CHF2 124 138
HFC-161 CH3CH2F 12 4
HFC-227ea CF3CHFCF3 3 220 3 350
HFC-236cb CH2FCF2CF3 1 340 1 210
HFC-236ea CHF2CHFCF3 1 370 1 330
HFC-236fa CF3CH2CF3 9 810 8 060
HFC-245ca CH2FCF2CHF2 693 716
HFC-245fa CHF2CH2CF3 1 030 858
HFC-365mfc CH3CF2CH2CF3 794 804

a Data source: IPCC's Fourth Assessment Report - Errata (IPCC 2012).

b Data source: IPCC, 2013: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp.  

Perfluorocarbons (HFCs) IPCC Global Warming Potentials - 100-Year Time Horizon
Greenhouse Gas Formula Fourth Assessment Reporta Fifth Assessment Reportb
Perfluoromethane CF4 7 390 6 630
Perfluoroethane C2F6 12 200 11 100
Perfluoropropane C3F8 8 830 8 900
Perfluorobutane C4F10 8 860 9 200
Perfluorocyclobutane c-C4F8 10 300 9 540
Perfluoropentane C5F12 9 160 8 550
Perfluorohexane C6F14 9 300 7 910
Perfluorodecalin C10F18 7 500 7 190
Perfluorocyclopropane c-C3F6 17 340 9 200

a Data source: IPCC's Fourth Assessment Report - Errata (IPCC 2012).

b Data source: IPCC, 2013: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp.  

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