Global warming potentials
All greenhouse gases (GHGs) are not equal. Each one has a unique atmospheric lifetime and heat-trapping potential.
The Global Warming Potential (GWP) metric examines each greenhouse gas’s ability to trap heat in the atmosphere compared to carbon dioxide (CO2). We measure this over a specified time horizon. Often, we calculate GHG emissions in terms of how much CO2 is essential to produce a similar warming effect over the chosen time horizon. This is the carbon dioxide equivalent (CO2 eq) value. We calculate it by multiplying the amount of gas by its accompanying global warming potential (GWP).
The Intergovernmental Panel on Climate Change (IPCC) provided 100-year GWPs in its Fifth Assessment Report. These GWPs are consistent with Decision 18/CMA.1 They are required for inventory reporting under the United Nations Framework Convention on Climate Change (UNFCCC). GWPs are also required to be used for facility GHG reporting under Section 46 of the Canadian Environmental Protection Act. The updated values from the IPCC’s Fifth Assessment report apply to facility GHG reporting, as of the calendar year 2022.
Global warming potentials for greenhouse gases
Greenhouse Gas | Formula | Fourth Assessment Reporta | Fifth Assessment Reportb |
---|---|---|---|
Carbon dioxide | CO2 | 1 | 1 |
Methane | CH4 | 25 | 28 |
Nitrous oxide | N2O | 298 | 265 |
Sulphur hexafluoride | SF6 | 22 800 | 23 500 |
Nitrogen trifluoride | NF3 | 17 200 | 16 100 |
- Data source: IPCC's Fourth Assessment Report - Errata (IPCC 2012).
- Data source: IPCC, 2013: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp.
Greenhouse Gas | Formula | Fourth Assessment Reporta | Fifth Assessment Reportb |
---|---|---|---|
HFC-23 | CHF3 | 14 800 | 12 400 |
HFC-32 | CH2F2 | 675 | 677 |
HFC-41 | CH3F | 92 | 116 |
HFC-43-10mee | CF3CHFCHFCF2CF3 | 1 640 | 1 650 |
HFC-125 | CHF2CF3 | 3 500 | 3 170 |
HFC-134 | CHF2CHF2 | 1 100 | 1 120 |
HFC-134a | CH2FCF3 | 1 430 | 1 300 |
HFC-143 | CH2FCHF2 | 353 | 328 |
HFC-143a | CH3CF3 | 4 470 | 4 800 |
HFC-152 | CH2FCH2F | 53 | 16 |
HFC-152a | CH3CHF2 | 124 | 138 |
HFC-161 | CH3CH2F | 12 | 4 |
HFC-227ea | CF3CHFCF3 | 3 220 | 3 350 |
HFC-236cb | CH2FCF2CF3 | 1 340 | 1 210 |
HFC-236ea | CHF2CHFCF3 | 1 370 | 1 330 |
HFC-236fa | CF3CH2CF3 | 9 810 | 8 060 |
HFC-245ca | CH2FCF2CHF2 | 693 | 716 |
HFC-245fa | CHF2CH2CF3 | 1 030 | 858 |
HFC-365mfc | CH3CF2CH2CF3 | 794 | 804 |
- Data source: IPCC's Fourth Assessment Report - Errata (IPCC 2012).
- Data source: IPCC, 2013: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp.
Greenhouse Gas | Formula | Fourth Assessment Reporta | Fifth Assessment Reportb |
---|---|---|---|
Perfluoromethane | CF4 | 7 390 | 6 630 |
Perfluoroethane | C2F6 | 12 200 | 11 100 |
Perfluoropropane | C3F8 | 8 830 | 8 900 |
Perfluorobutane | C4F10 | 8 860 | 9 200 |
Perfluorocyclobutane | c-C4F8 | 10 300 | 9 540 |
Perfluoropentane | C5F12 | 9 160 | 8 550 |
Perfluorohexane | C6F14 | 9 300 | 7 910 |
Perfluorodecalin | C10F18 | 7 500 | 7 190 |
Perfluorocyclopropane | c-C3F6 | 17 340 | 9 200 |
- Data source: IPCC's Fourth Assessment Report - Errata (IPCC 2012).
- Data source: IPCC, 2013: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 1535 pp.
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